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Alli is a weight loss medication that’s approved by the U.S. Food and Drug Administration for over-the-counter sale. Mixing weight loss medications with similar medications isn’t recommended, cautions the Weight-control Information Network, or WIN, an information service of the National Institutes of Health. Taking additional weight loss supplements can be dangerous, too. However, you can take Alli with one specific supplement — and in fact, this is a must-do if you use this particular diet aid.